Test of nonequilibrium thermodynamics in glassy systems: the soft-sphere case.

نویسندگان

  • E La Nave
  • F Sciortino
  • P Tartaglia
  • M S Shell
  • P G Debenedetti
چکیده

The scaling properties of the soft-sphere potential allow the derivation of an exact expression for the pressure of a frozen liquid, i.e., the pressure corresponding to configurations which are local minima in its multidimensional potential energy landscape. The existence of such a relation offers the unique possibility for testing the recently proposed extension of the liquid free energy to glassy out-of-equilibrium conditions and the associated expression for the temperature of the configurational degrees of freedom. We demonstrate that the nonequilibrium free energy provides an exact description of the soft-sphere pressure in glass states.

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عنوان ژورنال:
  • Physical review. E, Statistical, nonlinear, and soft matter physics

دوره 68 3 Pt 1  شماره 

صفحات  -

تاریخ انتشار 2003